Przemysław Furman1, Katarzyna Styszko This email address is being protected from spambots. You need JavaScript enabled to view it.2, Alicja Skiba1, Damian Zięba1, Mirosław Zimnoch1, Magdalena Kistler3, Anne Kasper-Giebl3, Stefania Gilardoni4 

1 AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, Department of Applied Nuclear Physics, Krakow, Poland
2 AGH University, Faculty of Energy and Fuels, Department of Coal Chemistry and Environmental Sciences, Krakow, Poland
3 TU Wien, Institute of Chemical Technologies and Analytics, Vienna, Austria
4 Institute of Polar Sciences-National Research Council, Bologna, Italy


 

Received: May 14, 2020
Revised: October 20, 2020
Accepted: November 1, 2020

 Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.


Download Citation: ||https://doi.org/10.4209/aaqr.2020.05.0223  


Cite this article:

Furman, Pr., Styszko, A., Skiba, l., Zięba, D., Zimnoch, M., Kistler, M., Kasper-Giebl, A. and Gilardoni, S. (2020). Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland. Aerosol Air Qual. Res. https://doi.org/10.4209/aaqr.2020.05.0223


HIGHLIGHTS

  • Seasonal variability of OC, EC, ions, PAHs were determined in PM at urban area.
  • Co-combustion had an impact on emissions of tracer and PAHs.
  • 1,3,5-triphenylbenzene tracer is useful for investigating plastic co-combustion.
 

ABSTRACT


The objective of this research was to evaluate the seasonal variation of the chemical composition of PM10 including polycyclic aromatic hydrocarbons (PAHs) and 1,3,5-triphenylbenzene (135TPB), which is a well known marker of plastic combustion. The presented work is a part of the project concerning assessment of air quality of small cities around Krakow agglomeration. Monitoring campaign was conducted between February and October 2017 in Wadowice, a small city in Krakow agglomeration, South Poland. To widen the knowledge of Krakow's agglomeration air quality, other aerosol chemical components were analyzed. Ion chromatography (IC) was used for analysis of cations and anions, while gas chromatography-mass spectrometry (GC-MS) was used for PAHs. Samples were also analyzed for OC/EC (organic/elemental carbon) by thermal-optical analysis with a Sunset Laboratory carbon analyzer, Sunset Inc. The co-combustion of plastic in addition to conventional fuels and the respective impact on air quality is evaluated via the concentration of the marker compound 135TPB. Co-combustion of plastics with fuels resulted in a higher abundance of fluorene and most of 4-6 ring PAHs, in agreement with recent literature. Authors proved that other sources besides plastic burning, including road transport, residential heating, residential combustion, industrial emissions, affect the air quality in South Poland. The modeling tool Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT), developed by NOAA’s Air Resources Laboratory, was used to define the possible areas outside Wadowice contributing to urban air pollution.


Keywords: Atmospheric aerosols; PAHs; 1,3,5-triphenylbenzene; Ions; OC/EC.




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