Mriganka Sekhar Biswas1,2, G. Pandithurai1, M.Y. Aslam1, Rohit D. Patil1, V. Anilkumar1, Shrikant D. Dudhambe1, Christophe Lerot3, Isebelle De Smedt3, Michel Van Roozendael3, Anoop S. Mahajan This email address is being protected from spambots. You need JavaScript enabled to view it.1

1 Indian Institute of Tropical Meteorology, Ministry of Earth Sciences, Pune, India
2 Savitribai Phule Pune University, Pune, India
3 Belgian Institute for Space Aeronomy, Brussels, Belgium


Received: May 4, 2020
Revised: November 16, 2020
Accepted: November 16, 2020

 Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.


Download Citation: ||https://doi.org/10.4209/aaqr.2020.05.0193  

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Cite this article:

Biswas, M.S., Pandithurai, G., Aslam, M.Y., Patil, R.D., Anilkumar, V., Dudhambe, S.D., Lerot, C., De Smedt, I., Van Roozendael, M., Mahajan, A.S. (2020). Effect of Boundary Layer Evolution on Nitrogen Dioxide (NO2) and Formaldehyde (HCHO) Concentrations at a High-altitude Observatory in Western India. Aerosol Air Qual. Res. https://doi.org/10.4209/aaqr.2020.05.0193


HIGHLIGHTS

  • Observations of nitrogen dioxide and formaldehyde at a high altitude site in India.
  • Both the trace gases show an increasing daytime diurnal profile throughout the day.
  • Observed trace gas diurnal profiles were unlike a photochemistry dominated profile.
  • Boundary layer evolution controls these diurnal profiles at this high altitude site.
 

ABSTRACT


Nitrogen dioxide (NO2) and formaldehyde (HCHO) are some of the most important trace gases in the atmosphere, acting as precursors for ozone formation and as pollutants at high concentrations. Although several observations of these species have been reported in the boundary layer, observations at high altitude sites are limited, especially in India. This study reports observations of NO2 and HCHO using the Multi AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) technique at the High Altitude Cloud Physics Laboratory (HACPL), Mahabaleshwar in the rural Western Ghats region of India. Measurements were conducted during the pre-monsoon season between 25th April and 30th May 2018. The average NO2 mixing ratio was 0.19 ± 0.06 ppb (range: 0.03 ppb to 0.69 ppb). Typically, NO2 mixing ratios were found to increase from early in morning and reached a maximum in the afternoon, contrary to an expected diurnal profile dominated by photochemistry. The average HCHO mixing ratio was 1.6 ± 0.61 ppb (range: 0.16 ppb to 4.5 ppb). HCHO mixing ratios also showed an increase from early in the morning and reach a maximum at ~3 pm in the afternoon after which a decrease was observed, peaking much later than expected from a photochemistry dominated profile. Using observations of the boundary layer height, back trajectories and the known photochemistry, we conclude that the observed diurnal variation in these two species is dominated by the mixing of emissions from the base of the mountain, resulting from the evolution of the boundary layer at the HACPL site.


Keywords: Formaldehyde (HCHO), Nitrogen dioxide (NO2), Boundary Layer (BL), India, Western Ghats.




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