Ernesto V. Gramsch This email address is being protected from spambots. You need JavaScript enabled to view it.1, Cristian R. Soto1, Pedro P. Oyola2, Felipe A. Reyes2, Yeanice Vasquez2, María A. Rubio3, Patricio A. Pérez1, Matías Tagle2

1 Physics Department, University of Santiago de Chile, Santiago, Chile
2 Mario Molina Center for Environmental Studies, Santiago, Chile
3 Facultad de Química y Biología and CEDENNA, Universidad de Santiago de Chile, Santiago, Chile


 

Received: November 2, 2018
Revised: April 22, 2020
Accepted: July 12, 2020

 Copyright The Author(s). This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are cited.


Download Citation: ||https://doi.org/10.4209/aaqr.2018.08.0318  

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Cite this article:

Gramsch, E.V., Soto, C.R., Oyola, P.P., Reyes, F.A., Vasquez, Y., Rubio, M.A., Pérez, P.A. and Tagle, M. (2020). Relationship between UV Energy and Formation of Secondary Particles in Santiago de Chile. Aerosol Air Qual. Res. 20: 2117–2127. https://doi.org/10.4209/aaqr.2018.08.0318


HIGHLIGHTS

  • New particles are formed primarily in summer.
  • There is a linear relationship between UV and new particles in summer.
  • In megacities, existing particles inhibit creation of new secondary particles.
 

ABSTRACT


Despite reduction efforts, the concentration of PM2.5 (particulate matter ≤ 2.5 µm in diameter) has remained steady or even grown slightly in Santiago, Chile, over the last few years. However, this potential increase may be due to the formation of secondary particles rather than a rise in primary emissions. Therefore, this study measured the size distribution of particulate matter with an Electrical Low Pressure Impactor (ELPI; Dekati) to investigate the generation of secondary ultrafine particles at several sites in this metropolitan area during 2013 and 2018. Little formation was detected during winter, but more activity was observed during fall, and the highest generation of these particles was found during summer, when the number of new particles between 10 and 20 nm in diameter displayed an obvious peak in the afternoon during periods of high solar radiation. Overall, no clear relationship was discerned between the secondary particle number and the UV radiation until the latter exceeded ~4.5 kJ m–2, when an almost linear correlation (R2 = 0.739) appeared. Additionally, the particle number exhibited a much lower correlation with the total solar energy, indicating that UV solar radiation plays the major role in ultrafine particle formation. However, these trends may only apply to polluted cities, which already contain elevated particulate matter concentrations. Also, the fact that secondary formation primarily occurs in Santiago during summer, when the PM2.5 level is low, confirms that large numbers of pre-existing particles inhibit the creation of new ones.


Keywords: Ultrafine particles; New particle formation; UV radiation.



Aerosol Air Qual. Res. 20 :2117 -2127 . https://doi.org/10.4209/aaqr.2018.08.0318  


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