Zeng-Yei Hseu1, Hsing-Cheng Hsi 2, Jhih-Siang Syu3, Li-Chun Wang4

  • 1 Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, 1, Shuefu Rd., Neipu, Pingtung 91201, Taiwan
  • 2 Graduate Institute of Environmental Engineering, National Taiwan University, 71 Chou-Shan Rd., Taipei 106, Taiwan
  • 3 Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, No.2, Jhuoyue Rd., Nanzih, Kaohsiung 811, Taiwan
  • 4 Chemical Systems Research Division, Chung-Shan Institute of Science and Technology, 481, Sec. Chia An, Zhongzheng Rd., Longtan Shiang, Taoyuan 325, Taiwan

Received: November 2, 2012
Revised: March 18, 2013
Accepted: March 18, 2013
Download Citation: ||https://doi.org/10.4209/aaqr.2012.11.0301  

  • Download: PDF


Cite this article:
Hseu, Z.Y., Hsi, H.C., Syu, J.S. and Wang, L.C. (2013). Development of Porous Template Carbons from Montmorillonite Clays and Evaluation of Their Toluene Adsorption Behaviors. Aerosol Air Qual. Res. 13: 1779-1789. https://doi.org/10.4209/aaqr.2012.11.0301


 

ABSTRACT


Carbon replicas were developed with two montmorillonites as the template and sucrose as the carbon source. The fabrication procedures included sucrose doping, polymerization with H2SO4, carbonization at 500–900°C, and liberation of carbon replicas from the template skeleton. N2 adsorption isotherms indicated the all of the resulting carbon replicas contained both micropores and mesopores. A higher carbonization temperature typically led to greater initial N2 adsorption, suggesting the presence of a greater number of micropores. Since no measurable micropores were found in the parent montmorillonites, those observed in the carbon replicas may have developed via activation of inherent water due to dehydration of montmorillonite clay or sucrose during the high temperature carbonization. XRD examination confirmed the formation of both graphite-like structure and amorphous carbon. The C content, C/H molar ratio, and the extent of π-electron resonance of the carbon replicas increased as the carbonization temperature rose, indicating that a higher temperature caused more thorough carbonization in the montmorillonite templates. Toluene adsorption experiments at 1000–8000 ppmv and 30–90°C demonstrated the effectiveness of carbon replicas with regard to capturing toluene. Model simulations further suggest that pore filling of toluene inside the mesopores of template carbon may occur, because the adsorption data showed better agreement with the DR model.


Keywords: Adsorption; Volatile organic compound; Template; Carbon replica; Montmorillonite


Share this article with your colleagues 

 

Subscribe to our Newsletter 

Aerosol and Air Quality Research has published over 2,000 peer-reviewed articles. Enter your email address to receive latest updates and research articles to your inbox every second week.

6.5
2021CiteScore
 
 
77st percentile
Powered by
Scopus
 
   SCImago Journal & Country Rank

2021 Impact Factor: 4.53
5-Year Impact Factor: 3.668

Aerosol and Air Quality Research partners with Publons

Aerosol and Air Quality Research partners with Publons

CLOCKSS system has permission to ingest, preserve, and serve this Archival Unit
CLOCKSS system has permission to ingest, preserve, and serve this Archival Unit

Aerosol and Air Quality Research (AAQR) is an independently-run non-profit journal that promotes submissions of high-quality research and strives to be one of the leading aerosol and air quality open-access journals in the world. We use cookies on this website to personalize content to improve your user experience and analyze our traffic. By using this site you agree to its use of cookies.