Articles online

Characteristics and Formation Mechanisms of Sulfate and Nitrate in Size-segregated Atmospheric Particles from Urban Guangzhou, China

Category: Aerosol and Atmospheric Chemistry

Volume: 19 | Issue: 6 | Pages: 1284-1293
DOI: 10.4209/aaqr.2018.07.0251
PDF | Supplemental material

Export Citation:  RIS | BibTeX

To cite this article:
Jiang, F., Liu, F., Lin, Q., Fu, Y., Yang, Y., Peng, L., Lian, X., Zhang, G., Bi, X., Wang, X. and Sheng, G. (2019). Characteristics and Formation Mechanisms of Sulfate and Nitrate in Size-segregated Atmospheric Particles from Urban Guangzhou, China. Aerosol Air Qual. Res. 19: 1284-1293. doi: 10.4209/aaqr.2018.07.0251.

Feng Jiang1,2, Fengxian Liu1,2, Qinhao Lin1, Yuzhen Fu1,2, Yuxiang Yang1,2, Long Peng1,2, Xiufeng Lian1,2, Guohua Zhang 1, Xinhui Bi1, Xinming Wang1, Guoying Sheng1

  • 1 State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
  • 2 University of Chinese Academy of Sciences, Beijing 100049, China


Polluted days favored SO42– formation in summer/autumn, but NO3 in winter/spring.
RH was only positively correlated with SOR at size range of 0.49–3.0 µm in winter.
Distinct mechanisms between seasons led to different size distributions of NO3.
NO2 likely plays a limited role in sulfate formation based on the calculated pH.


Various water-soluble inorganic compounds, including Na+, NH4+, K+, Ca2+, Mg2+, Cl, NO3, PO43– and SO42–, were analyzed in 130 sets of size-segregated (< 0.49, 0.49–0.95, 0.95–1.5, 1.5–3.0, 3.0–7.2 and 7.2–10.0 µm) aerosol samples collected from March 2013 to April 2014 in Guangzhou, China. SO42– was unimodally distributed and peaked during a typical droplet mode (0.49–0.95 µm). However, the distribution of NO3 significantly varied across the four seasons. It was unimodally distributed in summer and autumn, peaking in the coarse mode (3.0–7.2 µm), and bimodally distributed in winter and spring, peaking in the size ranges of 0.49–0.95 µm and 3.0–7.2 µm, respectively. The coarse-mode NO3 was mainly related to the influence of soil/dust. The additional mode during winter and spring was attributable to the formation of ammonium nitrate. Compared to clean days, polluted days favored the formation of SO42– in summer and autumn and NO3 in winter and spring. The sulfur oxidation ratios (SORs) for < 0.49, 0.49–0.95 and 0.95–1.5 µm particles were negatively correlated with the relative humidity (RH) in spring, summer and autumn, respectively. However, the SORs for 0.49–3.0 µm particles were positively correlated with the RH in winter, implying an important contribution from the aqueous oxidation of SO2. Further analysis shows that the SO42– in < 0.49 µm particles was formed primarily through gas-phase photochemical oxidation of SO2 during all four seasons. The formation of NO3 was mainly attributable to heterogeneous reactions for 1.5–3.0 µm particles year-round and homogeneous gas-phase reactions for < 0.49 µm particles in winter. Correlation analysis also indicates a positive influence from biomass burning on the formation of nitrate and sulfate. The average pH of PM3 was calculated to be 2.6–5.6. Thus, the aqueous oxidation of SO2 by NO2 plays a limited role in the formation of sulfate in the atmosphere of Guangzhou.


Water-soluble inorganic compounds Sulfate Nitrate Sulfur oxidation ratio Nitrogen oxidation ratio Guangzhou

Related Article

Chemical Characterisation of Sub-micron Aerosols During New Particle Formation in an Urban Atmosphere

Vijay P. Kanawade , Sachchida N. Tripathi , Abhishek Chakraborty, Huan Yu

Organic Nitrogen of Atmospheric Aerosols in the Coastal Area of Seto Inland Sea

Tokuhiro Nakamura , Yasushi Narita, Keizo Kanazawa, Mitsuo Uematsu
Accepted Manuscripts
DOI: 10.4209/aaqr.2019.12.0658

Typical and Atypical Morphology of Non-volatile Particles from a Diesel and Natural Gas Marine Engine

Alberto Baldelli , Una Trivanovic, Joel C. Corbin, Prem Lobo, Stephanie Gagné, J. Wayne Miller, Patrick Kirchen, Steven Rogak

Impact of Traffic Flows and Meteorological Events on the Hourly Elemental Composition of Fine and Coarse Particles at an Urban Site

Jose Nicolás , Franco Lucarelli, Nuria Galindo, Eduardo Yubero, Javier Crespo, Giulia Calzolai, Silvia Nava