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Impacts of New Particle Formation on Short-term Meteorology and Air Quality as Determined by the NPF-explicit WRF-Chem in the Midwestern United States

Category: Aerosol and Atmospheric Chemistry

Accepted Manuscripts
DOI: 10.4209/aaqr.2018.05.0163
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Can Dong1, Hitoshi Matsui2, Scott Spak3, Alicia Kalafut-Pettibone4, Charles Stanier 1

  • 1 Department of Chemical and Biochemical Engineering, University of Iowa, Iowa City, IA 52242, USA
  • 2 Department of Environmental Geochemical Cycle Research, Japan Agency for Marine-Earth Science and Technology, Yokohama 236-0001, Japan
  • 3 Public Policy Center, University of Iowa, Iowa City, IA 52242, USA
  • 4 Schafer, A Belcan Company, Arlington, VA 22203, USA

Highlights

Coupled meteorology, cloud chemistry, and PBL nucleation resolve novel feedbacks.
Expected results confirmed: more particles, more CCN at high supersaturation.
Unexpectedly, new particle formation impedes sulfur oxidation.
Cloud dimming effect identified in feedbacks involving cloud chemistry.


Abstract

New particle formation (NPF) from nucleation and subsequent nuclei growth are frequently observed in the troposphere, difficult to simulate, and of importance to aerosol-cloud interactions. In this work, regional simulations with the fully coupled NPF-explicit WRF-Chem model link NPF to cloud properties, and to changes in both meteorology and air quality in the Midwestern US for summer 2008. Simulations including NPF have higher concentrations of condensation nuclei as anticipated from the particle production associated with nucleation, leading to cloud condensation nuclei (CCN) concentration enhancement at high supersaturations. However, the online-coupled model develops a number of unexpected features that can be traced to a feedback loop involving aqueous (in-cloud) oxidation of sulfur combined with boundary layer NPF. Simulations with NPF (relative to simulations without) exhibit reduced PM2.5 sulfate mass, cloud dimming (reductions in cloud frequency, CCN concentration at low supersaturation, cloud optical depth, and cloud droplet number concentration), and enhanced shortwave radiation reaching the surface. This effect of NPF on PM2.5 mass is mostly absent for other constituents of PM2.5. Implications of this feedback loop, which is not considered in most climate and air quality modeling, are discussed.

Keywords

New particle formation Meteorology Air quality Sulfate WRF-Chem Aerosol cloud Interaction Indirect climate effect


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