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Elemental Composition and Source Apportionment of Fine and Coarse Particles at Traffic and Urban Background Locations in Athens, Greece

Category: Urban Air Quality

Accepted Manuscripts
DOI: 10.4209/aaqr.2017.12.0567
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Georgios Grivas 1,2, Stavros Cheristanidis2, Archontoula Chaloulakou2, Petros Koutrakis3, Nikos Mihalopoulos1,4

  • 1 Institute for Environmental Research and Sustainable Development, National Observatory of Athens, 15236 Athens, Greece
  • 2 School of Chemical Engineering, National Technical University of Athens, 15780 Athens, Greece
  • 3 Department of Environmental Health, Harvard T.H. Chan School of Public Health, Boston, MA 02115, USA
  • 4 Environmental Chemistry Processes Laboratory, Department of Chemistry, University of Crete, 71003 Heraklion, Greece

Highlights

Large roadside increments for toxic trace elements at fine and coarse size ranges.
Inter-site discrepancies in relative inputs of traffic and regional/secondary sources.
Natural sources account for 8–13% of PM10 indicating limits to regulatory compliance.
High inter-site temporal covariance but different levels of net source contributions.
Control of traffic emissions could produce significant effects for the greater area.


Abstract

Athens is one of the European cities most burdened by particle pollution, thus the characterization of aerosol composition and sources is imperative for addressing health concerns and undertaking mitigation measures. In this study, PM10 and PM2.5 ambient samples, collected at a roadside traffic and at an urban background site, throughout an annual period, were analyzed for elemental composition and light-absorbing carbon. Positive Matrix Factorization (PMF) analysis was performed to identify sources and quantify their contribution to PM2.5 and PM10-2.5 fractions. Over 2-fold roadside enhancement of concentrations was observed for a number of vehicle-emitted and road-dust resuspended species (BC, Cu, Zn, Fe, Ca), with increments for trace elements being more notable in the coarse fraction. Source apportionment indicated that for fine particles, road traffic and sulfate-rich regional aerosols were the key contributors, with the first being dominant at the roadside site (43%) and the latter accounting for the majority (52%) of particle mass at the background location. Other fine particle sources included biomass burning -mainly during wintertime-, heavy oil combustion, mineral dust and sea salt. For coarse particles, PMF-extracted factors were associated with vehicular emissions and road dust (prevailing at the roadside site, with a combined contribution of 60%), mineral dust and sea salt (52% cumulatively at the background site). Regional contributions of secondary and natural particles were comparable at level and well correlated among sites. On the contrary, net contributions of traffic related sources recorded large concentration gradients; however, high spatial correlations were observed, especially in case of favorable wind circulations from the city center towards the background site. It appears that control of traffic related emissions, in the absence of significant point sources in the area, could have a pronounced effect at a wide spatial scale within Athens, with broad implications for the protection of public health.

Keywords

PM2.5 PM10-2.5 XRF Spatial variability Receptor modelling


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