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Physicochemical Properties of Individual Airborne Particles in Beijing during Pollution Periods

Category: Aerosol and Atmospheric Chemistry

Article In Press
DOI: 10.4209/aaqr.2017.03.0116
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Wenhua Wang, Longyi Shao , Menglong Guo, Cong Hou, Jiaoping Xing, Fan Wu

  • State Key Laboratory of Coal Resources and Safe Mining, College of Geoscience and Surveying Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China


Year-long single particle samples were studied for the pollution days in Beijing.
Sulfate and mineral particles were dominated in the polluted day samples.
Sulfate particles showed highly positive correlation with relative humidity.
High pollution was mostly from local emissions and southern cities of Beijing.


Particulate pollution is a serious environmental problem in China and has received much attention from the public. Airborne particles were collected during haze days in Beijing from June 2013 to May 2014. The morphology and elemental composition were investigated with transmission electron microscopy coupled with energy dispersive X-ray spectrometry (TEM-EDX). Six types of individual particles were identified, including sulfate particles (35.1%), mineral particles (26.0%), metal particles (13.5%), fly ash (13.2%), organic particles (5.9%), and soot aggregates (5.7%). Non-carbonaceous particles are mainly “S-rich”, ranging from 37.4% in spring to 56.7% in summer, with certain amount of “Si-rich”, “Ca-rich”, “Fe-rich”, and “K-rich” particles. The relative number percentage of sulfate particles shows a positive correlation with relative humidity (RH), suggesting that high RH might accelerate the sulfation of individual particles. Based on air mass backward trajectories, the high pollution in Beijing might be influenced by local emissions and air masses from adjacent areas south of Beijing. Air masses from Inner Mongolia carry higher concentrations of mineral particles and alleviate the abundance of “S-rich” and other particles.


Pollution period Individual particle TEM-EDX Sulfate particles

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