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Chemical Characteristics of PM2.5 during 2015 Spring Festival in Beijing, China

Category: Aerosol and Atmospheric Chemistry

Volume: 17 | Issue: 5 | Pages: 1169-1180
DOI: 10.4209/aaqr.2016.08.0338
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Yangyang Zhang1, Jiaming Wei1, Aohan Tang 1, Aihua Zheng2, Zexi Shao1, Xuejun Liu1

  • 1 Beijing Key Laboratory of Farmland Soil Pollution Prevention and Remediation, College of Resources and Environmental Sciences, China Agricultural University, Beijing 100193, China
  • 2 Analytical and Testing Center, Beijing Normal University, Beijing 100875, China

Highlights

Spring Festival holiday effects on air pollution were evaluated in Beijing.
The air quality of non-haze days in holiday was better than that in non-holiday.
PM2.5 concentrations were ranked by the order of firework, haze and non-haze days.
Major ions were SO42–, NO3, NH4+ for haze days, SO42–, K+, Cl for firework days.
Major elements were classified into crustal, anthropogenic and fireworks elements.


Abstract

Air pollution especially of PM2.5 pollution is a serious problem in Beijing. In order to quantify the effect of a festival in which pollution was expected to be reduced, we collected and analyzed PM2.5 samples in urban Beijing during the 2015 Spring Festival (from February 9th to March 6th 2015). We divided the sampling period into three phases: non-haze, haze and firework days. The average concentration of PM2.5 was highest on firework days at 248.9 µg m–3, followed by haze days (199.9 µg m–3) and non-haze days (90.8 µg m–3). The air quality of non-haze days during the holiday was better than that during non-holiday periods. Secondary inorganic ions (SO42–, NO3 and NH4+) were enriched on the haze days, while those on firework days contained large amounts of Cl and K+, but small amounts of NO3 and NH4+. Ratios of NO3/SO42–, SO42–/K+ and Cl/K+ effectively distinguished the characteristics of PM2.5 between firework events and haze days. Ion balance calculations indicated that the acidity of PM2.5 from firework days was higher than that from haze and non-haze days. A method using enrichment factors (EF) found that crustal elements (EF < 10 on all three types of days) included Ca, Al, Fe, Na, Co, Ni, P, Ti, and V; firework elements (EF > 10 on firework days, significantly higher than haze days) were made up of Ba, Cr, Cu, Mg, Pb, S, Si, and Zn; common anthropogenic pollution elements (EF > 10 in all three types of days) were As, Cd, Cu, Pb, S, Sb, Zn. Differences in chemical characteristics indicated that holidays such as the Spring Festival can affect air pollution patterns in two ways: a decrease in the population and vehicles but an increase in activities such as firework displays.

Keywords

PM2.5 Chemical characteristics Fireworks Haze Spring Festival


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